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Corrosion
of steel reinforcement in concrete is an electrochemical process which
requires access of an electrolyte and oxygen to steel. Protective measures
against corrosion rely on minimizing or preventing the corrosive electrochemical
process. Four types of protective measures can be identified:
- Impeding access
of deleterious materials (water, oxygen, salts, carbon-dioxide etc.)
to the steel surface.
- Slowing the electrochemical
process through use of inhibitors.
- Modifying the
electrode through cathodic protection
- Providing coatings
to the steel reinforcement.
Galvanising - a
protector
Hot dip galvanizing
is a viable means of protecting reinforcement, particularly where the
durability of concrete cannot be guaranteed. Its use should be considered
for aggressive exposure conditions, precast construction and prestige
facades where long life, freedom from rust staining and low maintenance
are important criteria. Rust-stained surfaces and cracking and spalling
of concrete in recently completed structures demonstrate the wide need
to protect steel reinforcement.
Galvanized coatings
provide important advantages for the protection of reinforcement. Research
and practical experience since the 1950s have shown the corrosion resistance
of galvanized steel reinforcement to be superior to uncoated steel, while
the bond strengths of galvanized and black steel bars to concrete are
not significantly different.
The corrosion protection
of the galvanized coating ensures that the design strength of concrete
is maintained and the possibility of surface rust staining and eventual
corrosion of reinforcement and spalling of concrete is removed.
Steel accessories
for use in reinforced concrete structures, particularly fittings and inserts,
which may be partially exposed, are susceptible to the effects of corrosion
and should be galvanized.
Corrosion of reinforcement
Corrosion of steel
reinforcing bars inevitably weakens concrete members, reducing load bearing
capacity and safety factors. In extreme cases failure of reinforced concrete
members can occur, partly because of loss of strength due to corrosion
of the reinforcement itself, and partly because of the breaking up of
the concrete surrounding the reinforcement.
When steel reinforcements
corrodes, the corrosion product occupies more than three times the volume
of the original steel, exerting great disruptive tensile stress on the
surrounding conrete, leading to further cracking, more weather access
and further corrosion. In mild cases rust staining occurs, in more serious
cases, severe spalling of concrete may occur and ultimately concrete members
may fail completely.
In normal circumstances
uncoated steel reinforcing bars give satisfactory service provided the
following requirements are maintained:
- The design provides
for adequate concrete cover over the steel reinforcement.
- Precise placement
of reinforcement is maintained.
- Uniformly high
quality concrete is used.
- Complete compaction
of concrete is attained with no voids or pockets.
The benefits of galvanizing
reinforcement include:
- Protection to
steel during storage and construction prior to placing the concrete.
- Diminished effect
of variations in concrete quality.
- Safeguards against
poor workmanship, especially misplacement of reinforcement, poor compaction
and inadequate curing.
- Delayed initiation
of corrosion and the onset of cracking.
- Reduced likelihood
of surface staining.
- Increased structural
life of concrete, particularly where chloride contamination is likely.
Factors determining
the durability of reinforcement
Environment
The external environment
of the concrete provides the agents, which commonly cause corrosion in
reinforcement: water, oxygen, carbon dioxide and chloride ions.
Marine structures
and structures close to coastal waters are particularly at risk from corrosion
of reinforcement due to the ingress of chloride ions from sea spray and
salt-laden air.
Away from the seacoast
most corrosion of reinforcement in concrete is due to the process of carbonation,
which reduces the alkalinity of the surrounding concrete. This process
can occur at any geographic location. The rate of carbonation is at a
maximum when the relative humidity is about 50 per cent, and increases
with increasing temperature.
Surveys have shown
that the corrosion problem in relatively new buildings is worst in coastal
areas.
Carbonation resistance.
Galvanized reinforcement is better able to resist the effects of carbonation
because of the much wider range of pH (to about 8) over which the zinc
coating remains passivated. Since black steel typically depassivates when
the pH of concrete drops below about 11.5, it is apparent that as the
carbonation 'front' moves past a galvanized rebar, little or no effect
will occur until the concrete adjacent to the reinforcement is almost
completely neutralized.
Chloride tolerance.
Though zinc can be depassivated and attacked in the presence of chloride
ions, the tolerance of galvanized reinforcement to chloride depassivation
is substantially higher than that of black steel. In a survey of a number
of long-serving marine structures [Tonini, DE and Cook, AR (1978) `The
performance of galvanized reinforcement in high chloride environments
? field study reports.' International Corrosion Forum, NACE, Houston],
galvanized bars were shown to have been exposed to chloride contents as
high as 2.2 per cent (by approximately weight of cement) over periods
of 10-20 years, with less than 10 per cent loss of original coating thickness
and no record of failure. This should be compared to chloride levels in
the range of 0.2-0.3 per cent by weight of cement leading to severe corrosion
of black steel in similar circumstances.
Quality of concrete
In preventing corrosion
of reinforcement, the most critical property of concrete is permeability.
The degree of permeability determines the extent and rate of the diffusion
of chloride ions and carbon dioxide through the concrete. Permeability
is a function of mix design, compaction and curing.
Mix design.
To achieve low permeability, concrete must be dense, with a good bond
between aggregate and cement paste. These desirable characteristics can
be obtained by using good quality materials, with an adequate portland
cement content, a low water/cement ratio, and small sized, well graded
aggregates.
Compaction:
Proper compaction of concrete is of vital importance in minimizing permeability.
Problems are likely to arise when placing and vibrating techniques are
incorrect, reinforcement is congested, or form shapes that are not conducive
to the necessary flow of concrete during placement.
Curing. Proper
curing of concrete is essential to achieve low permeability, as the continued
hydration of the cement increases the volume of the gel and hence decreases
pore spaces and blocks capillaries. Proper field curing must be provided
for.
Depth of Cover
Lack of concrete cover
for reinforcement has been identified as a major problem associated with
`failures' in high rise buildings. In survey of 95 Sydney buildings ranging
in height from 5 to 36 storeys and aged between 2 and 17 years, the average
depth of concrete cover at sites where spalling occurred was 5.45 mm.
The maximum depth of cover at any failure point was 18 mm compared with
recommended covers in the range 25-30 mm, depending on the type of member.
Cracks in concrete
The type and size
of cracks have an important influence on durability of concrete. Cracks
caused by shrinkage or thermal stresses may contribute significantly to
reinforcement corrosion, particularly when they run parallel to reinforcing
bars and are close to the concrete surface.
Crack widths of less
than 0.1 mm are generally regarded as not causing significant corrosion
risk, provided cover is adequate and the structure is not exposed to highly
corrosive environments. Flexural cracks are not generally a problem as
they decrease in width from a maximum at the surface and become narrower
at the level of the reinforcing steel.
Surface treatment
of concrete
In the production
of architectural finishes the concrete surface is sometimes washed or
treated to expose the aggregate. These practices are not recommended if
there is any possibility of aggressive chemicals such as acids or salts
being left behind to permeate the concrete.
Etching, washing and
mechanical concrete surface finishing may also result in loss of the valuable
cement-rich paste which forms the surface layer of the concrete, reducing
carbonation resistance and depth of cover.
Reaction between
galvanized coatings and concrete
During initial contact
of galvanized reinforcement with wet concrete, the outer zinc layers of
the galvanized coating react to form stable insoluble zinc salts. Attack
ceases as the concrete hardens and the galvanized coating remains intact.
Corrosion protection
provided by galvanizing
In areas where the
reinforcement may be exposed accidentally due to thin or porous concrete,
cracking, or damage to the concrete, the galvanized coating provides extended
protection. Since the corrosion product of zinc occupies a smaller volume
than the corrosion products of iron, any small degree of corrosion, which
may occur to the galvanized coating, causes little or no disruption to
the surrounding concrete mass.
Studies were made
at the Structural Engineering Materials Laboratory, University of California,
Berkeley California, of the effects of corrosion on reinforced concrete
test prisms.
Prisms 300 x 100 x
100 mm were axially-reinforced with 19 mm diameter galvanized or black
steel bars. A 12.5 mm deep notch was cut at the mid section of each prism
to enforce formation of a crack at the notch should corrosion products
exert sufficient disruptive stresses. Prisms were placed in loading frames
and the steel reinforcing bars stressed to 140 MPa. Prisms were then subjected
to alternate immersion/drying cycles in a four per cent NaCI solution.
Cracks occurred in
test prisms reinforced with uncoated steel bars in less than ten months
exposure. Large crack areas had developed by about 18 months and were
still increasing at 24 months. No cracks were observed in prisms reinforced
with galvanized bars until almost 16 months exposure. These crack areas
were very small compared to those in prisms reinforced with uncoated steel
bars and crack development ceased after a further 2 1/2 months exposure.
Economics of galvanized
reinforcement in concrete
When the costs and
consequences of corrosion damage to a reinforced concrete building are
analysed, the extra cost of galvanizing is small. It can be regarded as
an `insurance premium', but a premium, which is low and need be paid once
only. Currently the cost of galvanizing of rebar is approximately Rs.80000
per tonne of steel and this depends on the quantity of steel to be galvanized,
bar diameter etc.
While the cost of
galvanizing is an important factor, the cost of galvanized reinforcement
as a percentage of total building cost is much lower than generally realised.
It is as low as 0.5 - 1.0 per cent in many cases; and this is the correct
life cycle costing approach to be adopted in such instances. For most
structures, even in the most aggressive environments, the use of galvanized
reinforcement can be confined to the exposed surfaces and critical structural
elements such as:
- Thin precast cladding
elements
- Facades of prestigious
buildings
- Surface exposed
beams and columns
- Window and door
surrounds
- Prefabricated units
- External facades
of buildings near the sea cost
- Architectural features
When related to total
project costs the added cost of galvanizing becomes very small indeed.
Such costs represent a very small proportion of the cost of repairs, should
unprotected reinforcement corrode. Frequently such repairs eliminate only
the visible damage and cannot be relied upon as a long-term solution.
Accordingly, whenever
there is concern that premature corrosion of reinforcement might occur,
reinforcement should be galvanized. The use of galvanizing however should
not be considered an alternative to the provision of an adequate cover
of dense, impermeable concrete.
Bond strength of
concrete to galvanized reinforcing bars
The results of extensive
programmes of pull-out testing by a number of researchers reveal no significant
difference in the bond strengths of black and galvanized steel deformed
(i.e ribbed) reinforcing bars in concrete.
The bond strength
to concrete has also been studied in tests conducted by University of
California in accordance with American Concrete Institute (ACI) standard
208-58. Both corroded and uncorroded rebar were used. Tests were done
on concrete beams with plain or; deformed bars cast inverted in the top
of the beam. Galvanized rebars showed equal or better bond strength than
ungalvanized rebars in all conditions in both plain and, deformed types.
Passivation and
additives
The research into
bond strengths also shows that there is little or no need for the current
practice of chromate passivation of galvanized reinforcement by the galvanizes
(other than to minimize the possibility of wet storage staining), or the
alternative addition of chromium trioxide to the concrete mix. The addition
of chromates to the concrete mix in the ratio of 35-150 ppm by weight
of cement increases the bond strength of galvanized plain bars significantly.
Application in
India
Convinced of the economic
and technical benefits of galvanized rebars, the Indian building and construction
sector has started using these in a number of projects. The following
are some of the known applications for galvanized rebars in India.
- Lotus Temple, New
Delhi - 300T
- Residential Building,
JNPT, Uran - 1000T
- All India Institute
of Physical Medical & Research, Haji Ali - 50T
- Residential Building,
Wadala - 50T
- Mahanagar Gas Ltd,
Mumbai - 50T
- Guest House, Mangalore
- 50T
- Central Railway,
Wadi Bunder - 450T
- Shree Anand Sukhram
Trust, Malad - 250T
Specifying galvanized
reinforcement
Reinforcing steel
should be specified to comply with Indian Standard IS:12594-1988 "Hot
DiP Zinc Coating on Structural Steel bars for Concrete Reinforcement-Specification".
India Lead Zinc Development
Association, has a vast repository of worldwide case histories using hot
dip galvanized steel reinforcement in RCC structures. ILZDA welcomes enquiries
from the civil engineering community on this emerging application.
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